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Redetermination of dicerium(III) Tris-(Sulfate) Tetra-Hydrate

Redetermination of dicerium(III) Tris-(Sulfate) Tetra-Hydrate

Xin Xu

Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 6;64(Pt 1):i1.

PMID: 21200451

Abstract:

Ce(2)(SO(4))(3)(H(2)O)(4) was obtained hydro-thermally from an aqueous solution of cerium(III) oxide, trimethyl-amine and sulfuric acid. The precision of the structure determination has been significantly improved compared with the previous result [Dereigne (1972 ▶). Bull. Soc. Fr. Mineral. Cristallogr.95, 269-280]. The coordination about the two Ce atoms is achieved by seven and six bridging O atoms from sulfate anions. Each S atom makes four S-O-Ce linkages through bridging O atoms. The coordination sphere of each Ce is completed by two water molecules, which act as terminal ligands.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP13550475	Cerium(III) sulfate hydrate		13550-47-5	Price

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