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Redox-controlled Hybridization of Helical Foldamers

Lara Faour, Catherine Adam, Christelle Gautier, Sébastien Goeb, Magali Allain, Eric Levillain, David Canevet, Marc Sallé

Chem Commun (Camb). 2019 May 14;55(40):5743-5746.

PMID: 31038524

Abstract:

Tetrathiafulvalene redox units were grafted at both extremities of an oligopyridine-dicarboxamide foldamer through a straightforward copper-catalyzed azide-alkyne cycloaddition. The present work demonstrates that the hybridization equilibrium of foldamers can be tuned through redox stimulations.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP31366253 Tetrathiafulvalene Tetrathiafulvalene 31366-25-3 Price
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