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Remarkable Thermodynamic Stability Toward Hydrolysis of Tripodal Titanium Alkoxides

Vesela Ugrinova, Gregory A Ellis, Seth N Brown

Chem Commun (Camb). 2004 Feb 21;(4):468-9.

PMID: 14765262

Abstract:

The monomeric titanium(IV) hydroxide complex, LTi(OH)(LH(3)= tris(2-hydroxy-3,5-di-tert-butylbenzyl)amine), which is sterically inhibited from condensation to a mu-oxo dimer, cannot be prepared by hydrolysis of the alkoxide, with K(eq)= 0.012 for hydrolysis of the titanium methoxide in THF.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP992927 Titanium(IV) methoxide Titanium(IV) methoxide 992-92-7 Price
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