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Rotational Polymorphism in 2-naphthalenethiol SAMs on Au(111)

Peng Jiang, Aymeric Nion, Alexandr Marchenko, Luc Piot, Denis Fichou

J Am Chem Soc. 2006 Sep 27;128(38):12390-1.

PMID: 16984169

Abstract:

We evidence by STM that 2-naphthalenethiol self-assembled monolayers formed at the n-tetradecane/Au(111) interface coexist as two structural phases which both possess molecules into two different orientations (standing and lying). Such a rotational polymorphism is observed and understood at the molecular level for the first time.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP91601 2-Naphthalenethiol 2-Naphthalenethiol 91-60-1 Price
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