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Silver-catalyzed Asymmetric Allylation: Allyltrimethoxysilane as a Remarkable Reagent

Hisashi Yamamoto, Manabu Wadamoto

Chem Asian J. 2007 Jun 4;2(6):692-8.

PMID: 17523136

Abstract:

Recently, there have been some reports on the use of allyltrimethoxysilane for enantioselective allylation with various metal fluorides or a combination of chiral complex and fluoride anion. These reactions can be applied not only to aldehydes but also to ketones and imines. In this Focus Review we discuss the development of asymmetric allylation with allyltrimethoxysilane catalyzed by chiral silver complexes.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP2551839 Allyltrimethoxysilane Allyltrimethoxysilane 2551-83-9 Price
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