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Simultaneous Production of P-Tolualdehyde and Hydrogen Peroxide in Photocatalytic Oxygenation of P-Xylene and Reduction of Oxygen With 9-mesityl-10-methylacridinium Ion Derivatives

Simultaneous Production of P-Tolualdehyde and Hydrogen Peroxide in Photocatalytic Oxygenation of P-Xylene and Reduction of Oxygen With 9-mesityl-10-methylacridinium Ion Derivatives

Kei Ohkubo, Kentaro Mizushima, Ryosuke Iwata, Kazunori Souma, Nobuo Suzuki, Shunichi Fukuzumi

Chem Commun (Camb). 2010 Jan 28;46(4):601-3.

PMID: 20062875

Abstract:

Photooxygenation of p-xylene by oxygen occurs efficiently under photoirradiation of 9-mesityl-2,7,10-trimethylacridinium ion (Me(2)Acr(+)-Mes) to yield p-tolualdehyde and hydrogen peroxide, which is initiated via photoinduced electron transfer of Me(2)Acr(+)-Mes to produce the electron-transfer state.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP104870	p-Tolualdehyde		104-87-0	Price

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