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Single Molecule Magnet Behaviour in a Rare Trinuclear {Cr(III)Dy} Methoxo-Bridged Complex

Pierre-Emmanuel Car, Annaïck Favre, Andrea Caneschi, Roberta Sessoli

Dalton Trans. 2015 Sep 28;44(36):15769-73.

PMID: 26282265

Abstract:

The reaction of the chromium(iii) chloride tetrahydrofuran complex with the dipivaloylmethane ligand, the lanthanide alcoholic salt DyCl3·CH3OH and the 1,1,1-tris(hydroxymethyl)-ethane ligand resulted in the formation of a new trinuclear chromium-dysprosium complex. Magnetic investigations revealed that the new 3d-4f complex exhibits single molecule magnet behaviour.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP10025748 Dysprosium(III) chloride Dysprosium(III) chloride 10025-74-8 Price
AP10170680 Chromium(III) chloride tetrahydrofuran complex (1:3) Chromium(III) chloride tetrahydrofuran complex (1:3) 10170-68-0 Price
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