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Six-coordinate Mononuclear Dysprosium(iii) Single-Molecule Magnets With the Triphenylphosphine Oxide Ligand

Kuduva R Vignesh, Dimitris I Alexandropoulos, Haomiao Xie, Kim R Dunbar

Dalton Trans. 2020 Apr 15;49(15):4694-4698.

PMID: 32236206

Abstract:

Structural, magnetic and theoretical studies of three octahedral mononuclear DyIII complexes with triphenylphosphine oxide and halide ligands are reported. The Cl- and Br- analogues exhibit SMM behavior with energy barriers of 49.1 K and 70.9 K, respectively under a small dc field. Ab initio calculations were performed, the results of which predict higher energy barriers for iodide containing SMMs.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP1308878 Dysprosium(III) oxide Dysprosium(III) oxide 1308-87-8 Price
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