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Slow Atmospheric Oxidation of Diphenylzinc: Di-Mu-Phenoxido-Bis[(diethyl ether)phenylzinc(II)]

Anders Lennartson, Mikael Håkansson

Acta Crystallogr C. 2008 Jan;64(Pt 1):m10-2.

PMID: 18216427

Abstract:

The title compound, [Zn2(C6H5)2(C6H5O)2(C4H10O)2], was isolated from a solution of diphenylzinc in diethyl ether that had been exposed to air. The molecules are dinuclear, with a distorted tetrahedral coordination geometry around the Zn atoms and with molecules situated about a crystallographic inversion centre. Molecules associate via three sets of C-H...pi(arene) interactions, leading to a network structure.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP1078586 Diphenylzinc Diphenylzinc 1078-58-6 Price
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