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Solute-solvent and Solvent-Solvent Interactions in the Preferential Solvation of 4-[4-(dimethylamino)styryl]-1-methylpyridinium Iodide in 24 Binary Solvent Mixtures

Solute-solvent and Solvent-Solvent Interactions in the Preferential Solvation of 4-[4-(dimethylamino)styryl]-1-methylpyridinium Iodide in 24 Binary Solvent Mixtures

Tharly Bevilaqua, Thaini F Gonçalves, Cristina de G Venturini, Vanderlei G Machado

Spectrochim Acta A Mol Biomol Spectrosc. 2006 Nov;65(3-4):535-42.

PMID: 16524763

Abstract:

The molar transition energy (E(T)) polarity values for the dye 4-[4-(dimethylamino)styryl]-1-methylpyridinium iodide were collected in binary mixtures comprising a hydrogen-bond accepting (HBA) solvent (acetone, acetonitrile, dimethyl sulfoxide (DMSO), and N,N-dimethylformamide (DMF)) and a hydrogen-bond donating (HBD) solvent (water, methanol, ethanol, propan-2-ol, and butan-1-ol). Data referring to mixtures of water with alcohols were also analyzed. These data were used in the study of the preferential solvation of the probe, in terms of both solute-solvent and solvent-solvent interactions. These latter interactions are of importance in explaining the synergistic behavior observed for many mixed solvent systems. All data were successfully fitted to a model based on solvent-exchange equilibria. The E(T) values of the dye dissolved in the solvents show that the position of the solvatochromic absorption band of the dye is dependent on the medium polarity. The solvation of the dye in HBA solvents occurs with a very important contribution from ion-dipole interactions. In HBD solvents, the hydrogen bonding between the dimethylamino group in the dye and the OH group in the solvent plays an important role in the solvation of the dye. The interaction of the hydroxylic solvent with the other component in the mixture can lead to the formation of hydrogen-bonded complexes, which solvate the dye using a lower polar moiety, i.e. alkyl groups in the solvents. The dye has a hydrophobic nature and a dimethylamino group with a minor capability for hydrogen bonding with the medium in comparison with the phenolate group present in Reichardt's pyridiniophenolate. Thus, the probe is able to detect solvent-solvent interactions, which are implicit to the observed synergistic behavior.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP2156298	2-[4-(Dimethylamino)styryl]-1-methylpyridinium iodide		2156-29-8	Price

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