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Solution Properties of Single-Walled Carbon Nanotubes

J Chen, MA Hamon, H Hu, Y Chen, AM Rao, PC Eklund, RC Haddon

Science. 1998 Oct 2;282(5386):95-8.

PMID: 9756485

Abstract:

Naked metallic and semiconducting single-walled carbon nanotubes (SWNTs) were dissolved in organic solutions by derivatization with thionychloride and octadecylamine. Both ionic (charge transfer) and covalent solution-phase chemistry with concomitant modulation of the SWNT band structure were demonstrated. Solution-phase near-infrared spectroscopy was used to study the effects of chemical modifications on the band gaps of the SWNTs. Reaction of soluble SWNTs with dichlorocarbene led to functionalization of the nanotube walls.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
LS71706 Carbon nanotube, single-walled, octadecylamine functionalized Carbon nanotube, single-walled, octadecylamine functionalized Price
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