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Stir-bar-sorptive Extraction and Ultra-High-Performance Liquid Chromatography-Tandem Mass Spectrometry for Simultaneous Analysis of UV Filters and Antimicrobial Agents in Water Samples

Stir-bar-sorptive Extraction and Ultra-High-Performance Liquid Chromatography-Tandem Mass Spectrometry for Simultaneous Analysis of UV Filters and Antimicrobial Agents in Water Samples

Marta Pedrouzo, Francesc Borrull, Rosa Maria Marcé, Eva Pocurull

Anal Bioanal Chem. 2010 Aug;397(7):2833-9.

PMID: 20428847

Abstract:

Stir-bar-sorptive extraction (SBSE) with liquid desorption (LD) and ultra-high-performance liquid chromatography-electrospray ionization triple-quadrupole tandem mass spectrometry (UHPLC-(ESI)MS-MS) were used for analysis of six personal care products in environmental water: four UV filters (2,2-dihydroxy-4-methoxybenzophenone, benzophenone-3, octocrylene, and octyldimethyl-p-aminobenzoic acid) and two antimicrobial agents (triclocarban and triclosan). Experimental conditions that affect SBSE-LD sorption efficiency (extraction time and temperature, sample pH, and ionic strength) and desorption efficiency (solvent, temperature, and time) were optimized. The method proved to be sensitive--a 50-mL sample was used to determine these compounds in environmental waters at trace levels. The detection limits of the analytical method were 2.5 ng L(-1) for river water and 5-10 ng L(-1) for effluent and influent sewage water. In river waters, benzophenone-3 was found at levels from 6 ng L(-1) to 28 ng L(-1) and triclosan at levels

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AS24901	Octocrylene-(2-ethyl-d5-hexyl-2,3,3,4,4,5,5,6,6,6-d10)			Price

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