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Studies on Influence of Cd(2+) Ions in Unidirectional Growth and Characterization of l-Cysteine Hydrochloride Monohydrate Single Crystals

P V Prasad, T K Visweswara Rao, K Ramachandra Rao, Ch Satya Kamal, T Samuel

Spectrochim Acta A Mol Biomol Spectrosc. 2015 Feb 5;136 Pt C:1950-4.

PMID: 25467690

Abstract:

Cadmium doped l-Cysteine hydrochloride monohydrate (Cd(2+)-C3H7NO2S⋅HCl⋅H2O), a non-linear optical crystal, was grown by conventional as well as unidirectional solution growth techniques. While the dimension of the conventionally grown crystal was 16×14×5mm(3), the dimension of the crystal grown unidirectional method was 32mm long and 6mm diameter. The grown crystals were studied using XRD for phase analysis, HRXRD for crystalline perfection and UV-Vis NIR spectroscopy for optical properties. The high crystalline perfection was found in the crystal grown by unidirectional method than that grown by conventional one. FTIR study indicates that Cd(2+) ion was coordinated to l-Cysteine⋅HCl⋅H2O through S ligand. The nonlinear optical character of the title compound was observed by measuring the SHG efficiency, which is 1.35times to that of KDP by Kurtz technique.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP7048046-B L-Cysteine hydrochloride monohydrate L-Cysteine hydrochloride monohydrate 7048-04-6 Price
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