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Sulfamic Acid-Catalyzed Lead Perovskite Formation for Solar Cell Fabrication on Glass or Plastic Substrates

Sulfamic Acid-Catalyzed Lead Perovskite Formation for Solar Cell Fabrication on Glass or Plastic Substrates

Yunlong Guo, Wataru Sato, Kazutaka Shoyama, Eiichi Nakamura

J Am Chem Soc. 2016 Apr 27;138(16):5410-6.

PMID: 27054265

Abstract:

Lead perovskite materials such as methylammonium triiodoplumbate(II) (CH3NH3PbI3, PV) are promising materials for printable solar cell (SC) applications. The preparation of PV involves a series of energetically costly cleavages of the μ-iodo bridges via conversion of a mixture of PbI2 (PI) and methylammonium iodide (CH3NH3I, MAI) in N,N-dimethylformamide (DMF) into a precursor solution containing a polymeric strip of a plumbate(II) dimer [(MA(+))2(PbI3(-))2·(DMF)2]m, which then produces a perovskite film with loss of DMF upon spin-coating and heating of the substrate. We report here that the PI-to-PV conversion and the PV crystal growth to micrometer size can be accelerated by a small amount of zwitterionic sulfamic acid (NH3SO3, SA) and that sulfamic acid facilitates electron transfer to a neighboring electron-accepting layer in an SC device. As a result, an SC device on indium tin oxide (ITO)/glass made of a 320 nm thick PV film using 0.7 wt % SA showed a higher short-circuit current, open-circuit voltage, and fill factor and hence a 22.5% higher power conversion efficiency of 16.02% compared with the device made without SA. The power conversion efficiency value was reproducible (±0.3% for 25 devices), and the device showed very small hysteresis. The device without any encapsulation showed a respectable longevity on a shelf under nitrogen under ambient light. A flexible device similarly fabricated on ITO/poly(ethylene naphthalate) showed an efficiency of 12.4%.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
LS72719	Methylammonium triiodoplumbate(II) precursor solution			Price
LS72750	Methylammonium chlorodiiodoplumbate(II) precursor solution			Price

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