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Synthesis and Characterization of Germanium Coordination Compounds for Production of Germanium Nanomaterials

Synthesis and Characterization of Germanium Coordination Compounds for Production of Germanium Nanomaterials

Timothy J Boyle, Louis J Tribby, Leigh Anna M Ottley, Sang M Han

Eur J Inorg Chem. 2009 Dec 1;2009(36):5550-5560.

PMID: 23555180

Abstract:

A series of novel germanium(II) precursors was synthesized to initiate an investigation between the precursors' structures and the morphologies of the resulting nanoparticles. The precursors were synthesized from the reaction of Ge[N(SiMe3)2]2 or [Ge(OBut)2]2 and the appropriate ligand: N,N'-dibenzylethylenediamine (H2-DBED), tert-butanol (H-OBut), 2,6-di-methyl phenol (H-DMP), 2,6-di-phenyl phenol (H-DPP), tert-butyldimethylsilanol (H-DMBS), triphenylsilanol (H-TPS), triphenylsilanethiol (H-TPST), and benzenethiol (H-PS). The products were identified as: [Ge(μc-DBED)]2 (1, μc= bridging chelating), [Ge(μ-DMP)(DMP)]2 (2), Ge(DPP)2 (3), [Ge(μ-OBut)(DMBS)]2, (4), [Ge(μ-DMBS)(DMBS)]2 (5), Ge(TPS)3(H) (6), [Ge(μ-TPST)(TPST)]2 (7), and Ge(PS)4 (8). The Ge(II) metal centers were found to adopt a pyramidal geometry for 1, 2, 4, 5, 7, a bent arrangement for 3, and a tetrahedral coordination for the Ge(IV) species 6 and 8. Using a simple solution precipitation methodology, Ge(0) nanomaterials were isolated as dots and wires for the majority of precursors. Compound 7 led to the isolation of amorphous GexSy. The nanomaterials isolated were characterized by TEM, EDS, and powder XRD. A correlation between the precursor's arrangement and final observed nanomorphology was proffered as part of the 'precursor structure affect' phenomenon.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP14606429	Triphenylsilanethiol		14606-42-9	Price
AP18173643	tert-Butyldimethylsilanol		18173-64-3	Price

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