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Synthesis and Characterization of Silylated Phosphonium [P(OSiMe 3) 4] + and Phosphate [O 2 P(OSiMe 3) 2] - Salts

Synthesis and Characterization of Silylated Phosphonium [P(OSiMe 3) 4] + and Phosphate [O 2 P(OSiMe 3) 2] - Salts

Paul Felgenhauer, René Labbow, Axel Schulz, Alexander Villinger

Inorg Chem. 2018 Aug 6;57(15):9348-9353.

PMID: 29985595

Abstract:

Starting from an optimized synthesis of silylated phosphoric acid, OP(OSiMe3)3, a borate salt bearing the [P(OSiMe3)4]+ cation was generated in the reaction of OP(OSiMe3)3 with [Me3Si-H-SiMe3][B(C6F5)4], isolated, and fully characterized. Analogously to the protonated species, phosphoric acid (H3PO4) reaction of OP(OSiMe3)3 with a base led to the formation of the unknown [O2P(OSiMe3)2]- anion, which could be crystallized as potassium salt and structurally characterized, too. Both [P(OSiMe3)4]+ and [O2P(OSiMe3)2]- can be regarded as the formal autoprotolysis products of OP(OSiMe3)3.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP1241684285	16-α-Hydroxyestrone-2,3,4-13C3		1241684-28-5	Price

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