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Synthesis and Electric Properties of a Two-Dimensional Metal-Organic Framework Based on Phthalocyanine

Synthesis and Electric Properties of a Two-Dimensional Metal-Organic Framework Based on Phthalocyanine

Hisanori Nagatomi, Nobuhiro Yanai, Teppei Yamada, Kanji Shiraishi, Nobuo Kimizuka

Chemistry. 2018 Feb 6;24(8):1806-1810.

PMID: 29291261

Abstract:

Complexation of copper(II) 2,3,9,10,16,17,23,24-octahydroxy-29H,31H-phthalocyanine (CuPcOH) with copper(II) ions gives a two-dimensional (2D) metal-organic framework (MOF). This is the first report of a phthalocyanine-based MOF. This 2D MOF was obtained as a black powder and showed an electrical conductivity of 1.6×10-6 S cm-1 at 80 °C. When this MOF is used as a cathode of lithium ion battery (LIB), large charge/discharge capacities of 151/128 mAh g-1 were obtained. In addition, it showed a good stability during 200 charge/discharge cycles. The obtained LIB performance mainly originates from the electrically conductive and redox-active framework of the phthalocyanine-based 2D MOF and its hierarchical microporous/mesoporous structure.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP15275522	Copper(II) 4,4′,4′′,4′′′-tetraaza-29H,31H-phthalocyanine		15275-52-2	Price

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