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Synthesis and Structural Characterization of the First Unsymmetrical Diarylpalladium Complex trans-Pd(C6F5)(2,4,6-C6F3H2)(PEt3)2, Derived From Transmetallation Between 2,4,6-trifluorophenylboronic Acid and trans-Pd(C6F5)I(PEt3)2

Synthesis and Structural Characterization of the First Unsymmetrical Diarylpalladium Complex trans-Pd(C6F5)(2,4,6-C6F3H2)(PEt3)2, Derived From Transmetallation Between 2,4,6-trifluorophenylboronic Acid and trans-Pd(C6F5)I(PEt3)2

Yasushi Nishihara, Hiroyuki Onodera, Kohtaro Osakada

Chem Commun (Camb). 2004 Jan 21;(2):192-3.

PMID: 14737544

Abstract:

The reactions of 2,4,6-trifluorophenylboronic acid with aryl(iodo)palladium(ii) complexes, trans-Pd(C(6)F(5))I(PR(3))(2)(PR(3)= PEt(3), PMe(2)Ph, PMePh(2)) in the presence of Ag(2)O afforded trans-Pd(C(6)F(5))(2,4,6-C(6)F(3)H(2))(PR(3))(2) which are stabilized by fluorine atoms in the ortho positions.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP247564712	2,3,6-Trifluorophenylboronic acid		247564-71-2	Price
AP871125701	3-Propoxy-2,4,6-trifluorophenylboronic acid		871125-70-1	Price

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