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Synthesis and Structure of Air-Stable Lewis Acidic Binuclear Complex of Zirconocene Pentafluorophenylsulfonate and Its Catalytic Application in the Allylation of Carbonyl Compounds With Tetraallyltin

Renhua Qiu, Xinhua Xu, Yinhui Li, Guoping Zhang, Lingling Shao, Delie An, Shuangfeng Yin

Chem Commun (Camb). 2009 Apr 7;(13):1679-81.

PMID: 19294260

Abstract:

Air-stable Lewis acidic micro2-hydroxy bridged binuclear complex of zirconocene pentafluorophenylsulfonate was successfully synthesized and found to show high catalytic efficiency in chemoselective allylation of carbonyl compounds with tetraallyltin in aqueous methanol media.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP7393433 Tetraallyltin Tetraallyltin 7393-43-3 Price
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