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Synthesis and Structure of Zr(iv)- And Ce(iv)-based CAU-24 With 1,2,4,5-tetrakis(4-carboxyphenyl)benzene

Synthesis and Structure of Zr(iv)- And Ce(iv)-based CAU-24 With 1,2,4,5-tetrakis(4-carboxyphenyl)benzene

M Lammert, H Reinsch, C A Murray, M T Wharmby, H Terraschke, N Stock

Dalton Trans. 2016 Dec 21;45(47):18822-18826.

PMID: 27840878

Abstract:

Two new MOFs denoted as M-CAU-24 (M = Zr, Ce) based on 1,2,4,5-tetrakis(4-carboxyphenyl)benzene (H4TCPB) were obtained under mild reaction conditions within 15 min. The MOFs with composition [M6(μ3-O)4(μ3-OH)4(OH)4(H2O)4(TCPB)2] crystallise in the scu topology, a connectivity hitherto unreported for Zr-MOFs with tetracarboxylate linker molecules. Zr-CAU-24 exhibits UV/blue ligand-based luminescence.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
LS72549	1,2,4,5-Tetrakis(4-carboxyphenyl)benzene			Price

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