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Synthesis and Suzuki-Miyaura Cross-Coupling Reactions of Potassium Boc-protected Aminomethyltrifluoroborate With Aryl and Hetaryl Halides

Gary A Molander, Inji Shin

Org Lett. 2011 Aug 5;13(15):3956-9.

PMID: 21732595

Abstract:

Potassium Boc-protected aminomethyltrifluoroborate, a primary aminomethyl equivalent, was synthesized successfully through a "one-pot" process. With this trifluoroborate, Suzuki-Miyaura cross-coupling reactions were investigated with a variety of both aryl and hetaryl chlorides in good to excellent yields.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
LS7931444 [(tert-Butylammonio)methyl]trifluoroborate [(tert-Butylammonio)methyl]trifluoroborate Price
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