Home
Resources
Publications
Synthesis, Crystal Structure, and Catalytic Property of Dioxomolybdenum(VI) Complex Derived From 4-Bromo-N'-(4-diethylamino-2-hydroxybenzylidene) Benzohydrazide

Synthesis, Crystal Structure, and Catalytic Property of Dioxomolybdenum(VI) Complex Derived From 4-Bromo-N'-(4-diethylamino-2-hydroxybenzylidene) Benzohydrazide

Li Wang, Yong-Jun Han, Li Qing-Bin, Ling-Wei Xue

Acta Chim Slov. 2016 Dec;63(4):822-826.

PMID: 28004100

Abstract:

A novel dioxomolybdenum(VI) complex, [MoO2L(MeOH)], where L is the anion of 4-bromo-N'-(4-diethylamino-2-hydroxybenzylidene)benzohydrazide, has been synthesized and characterized by physico-chemical methods and single crystal X-ray determination. In the complex the Mo atom is in octahedral coordination, with three donor atoms of the hydrazone ligand, two oxo groups, and one methanol O atom. The complex exhibits catalytic property for the sulfoxidation reactions. In the presence of the complex a 93% conversion of the sulfide to the corresponding sulfoxide was observed within 60 min and the 100% conversion was achieved after 2 h.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP100139546	4-(Diethylamino)benzhydrazide		100139-54-6	Price

As a specialist in analytical chemical Products, Alfa Chemistry offers consumers a wealth of raw materials and a full range of technologies and services.

QUICK LINKS

HEADQUARTERS

Tel:

Fax:

Email: