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Synthesis of 1,10-dimethylbicyclo[8.8.8]hexacosane and 1,10-dihydroxybicyclo[8.8.8]hexacosane

Ian W Jones, Yasunari Monguchi, Alice Dawson, Michael D Carducci, Eugene A Mash

Org Lett. 2005 Jul 7;7(14):2841-3.

PMID: 15987150

Abstract:

[structure: see text] 1,10-Dimethylbicyclo[8.8.8]hexacosane (1) and 1,10-dihydroxybicyclo[8.8.8]hexacosane (2) were prepared in 4% yield over seven steps and in 18% yield over three steps, respectively, starting from 1,10-cyclooctadecanedione. The identities and out,out conformations of these compounds were established by single-crystal X-ray analysis.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP630013 Hexacosane Hexacosane 630-01-3 Price
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