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Synthesis of an Acyltrifluoroborate and Its Fusion With Azides to Form Amides

Gary A Molander, Jessica Raushel, Noel M Ellis

J Org Chem. 2010 Jun 18;75(12):4304-6.

PMID: 20481486

Abstract:

A uniquely stable acyl potassium trifluoroborate, potassium (2-phenylacetyl)trifluoroborate, has been synthesized and isolated. In the presence of an activating Lewis acid, this reagent reacts with azides to form amides in good yields.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP1229039502 Potassium (2-phenylacetyl)trifluoroborate Potassium (2-phenylacetyl)trifluoroborate 1229039-50-2 Price
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