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Synthesis of Doubly Annulated m-Terphenyl-Based Molecular Tweezers and Their Charge-Transfer Complexes With DDQ as a Guest

Khushabu Thakur, Denan Wang, Sergey V Lindeman, Rajendra Rathore

Chemistry. 2018 Sep 6;24(50):13106-13109.

PMID: 30033629

Abstract:

The synthesis of a doubly-annulated m-terphenyl-based tweezer platform has been developed, which affords ready incorporation of various pincer units from monobenzenoid to polybenzenoid electron donors. The complexation study with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) as guest has been carried out, and the crystal structure of T-Py∩DDQ reveals the sandwich-type binding mode in the solid state.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP92068 m-Terphenyl m-Terphenyl 92-06-8 Price
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