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Synthesis of Ln(III) Chloride Tetraphenylporphyrin Complexes

Timothy J Foley, Khalil A Abboud, James M Boncella

Inorg Chem. 2002 Apr 8;41(7):1704-6.

PMID: 11925160

Abstract:

The isolation and identification of the first examples of anhydrous lanthanide chloride tetraphenylporphyrin complexes have been described. The purple complexes were generated by the reaction of dilithiotetraphenylporphyrin bis(dimethoxyethane) with lanthanide trichloride tris(tetrahydrofuran) salts to yield the products in up to 85% yield. The crystal structures for the holmium and ytterbium complexes are also presented.

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AP10138622 Holmium(III) chloride Holmium(III) chloride 10138-62-2 Price
AP10361918 Ytterbium(III) chloride Ytterbium(III) chloride 10361-91-8 Price
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