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Synthesis of Multifunctional Aryl(trifloxyalkenyl)iodonium Triflate Salts

Balázs L Tóth, Ferenc Béke, Orsolya Egyed, Attila Bényei, András Stirling, Zoltán Novák

ACS Omega. 2019 May 24;4(5):9188-9197.

PMID: 31460007

Abstract:

A convenient procedure for the synthesis of aryl(trifloxyalkenyl)iodonium triflate salts from commercially available (diacetoxyiodo)benzene, trimethylsilyl trifluoromethanesulfonate, and acetylenes under mild conditions was developed. The obtained multifunctional hypervalent vinyliodonium salts equipped with electrophilic and nucleophilic functions could serve as novel C2 synthons for organic transformations. The structure of the iodonium salts was identified by multidimensional NMR spectroscopy and X-ray crystallography.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP180801552 Boc-methoxyphenyldiphenylsulfonium triflate Boc-methoxyphenyldiphenylsulfonium triflate 180801-55-2 Price
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