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Synthesis of O-Carborane-Functionalized Metal-Organic Frameworks Through Ligand Exchanges for Aggregation-Induced Emission in the Solid State

Sangdon Choi, Ha-Eun Lee, Chan Hee Ryu, Jooyeon Lee, Jihyun Lee, Minyoung Yoon, Youngjo Kim, Myung Hwan Park, Kang Mun Lee, Min Kim

Chem Commun (Camb). 2019 Oct 1;55(79):11844-11847.

PMID: 31517359

Abstract:

The carborane (CB)-functionalized ligand was installed in a variety of MOFs through postsynthetic ligand exchange processes. This methodology is a general method for preparing o-CB-functionalized MOFs with known frameworks. Furthermore, the photoluminescence (PL) spectra revealed intriguing aggregation-induced emission (AIE) features following the systematic incorporation of o-CB functionalities into framework-type materials.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP16872096 o-Carborane o-Carborane 16872-09-6 Price
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