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Tetra-amminepalladium(II) Dichloride Ammonia Tetra-Solvate

Tobias Grassl, Nikolaus Korber

Acta Crystallogr Sect E Struct Rep Online. 2014 Jun 7;70(Pt 7):i32.

PMID: 25161505

Abstract:

The title compound, [Pd(NH3)4]Cl2·4NH3, was crystallized in liquid ammonia from the salt Pd(en)Cl2 (en is ethylenediamine) and is isotypic with [Pt(NH3)4]Cl2·4NH3 [Grassl & Korber (2014 ▶). Acta Cryst. E70, i31]. The Pd(2+) cation is coordinated by four ammonia mol-ecules, exhibiting a square-planar geometry. The chloride anions are surrounded by nine ammonia mol-ecules. These are either bound in the palladium complex or solvent mol-ecules. The packing of the ammonia solvent mol-ecules enables the formation of an extended network of N-H⋯N and N-H⋯Cl inter-actions with nearly ideal hydrogen-bonding geometry.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP15020992 (Ethylenediamine)palladium(II) chloride (Ethylenediamine)palladium(II) chloride 15020-99-2 Price
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