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Tetra-kis(μ-2-phen-oxy-propionato)-κO,O':O';κO:O,O',κO:O'-bis-[(1,10-phenanthroline-κN,N')(2-phen-oxy-propionato-κO,O')praseodymium(III)]

Tetra-kis(μ-2-phen-oxy-propionato)-κO,O':O';κO:O,O',κO:O'-bis-[(1,10-phenanthroline-κN,N')(2-phen-oxy-propionato-κO,O')praseodymium(III)]

Jin-Bei Shen, Jia-Lu Liu, Guo-Liang Zhao

Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1321.

PMID: 22058896

Abstract:

In the centrosymmetric binuclear title complex, [Pr(2)(C(9)H(9)O(3))(6)(C(12)H(8)N(2))(2)], the two Pr(III) ions are linked by four 2-phen-oxy-propionate (L) groups through their bi- and tridentate bridging modes. Each Pr(III) ion is nine-coordinated by one 1,10-phenanthroline mol-ecule, one bidentate carboxyl-ate group and four bridging carboxyl-ate groups in a distorted PrN(2)O(7) monocapped square-anti-prismatic geometry. The title compound is isotypic with its terbium- and dysprosium-containing analogues.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP7440100	Praseodymium		7440-10-0	Price

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