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Tetrabutylammonium Iodide Catalyzed Allylic Sulfonylation of Baylis-Hillman Acetates With Sulfonylhydrazides in Water

Xiaoqing Li, Xiangsheng Xu, Yucai Tang

Org Biomol Chem. 2013 Feb 13;11(10):1739-42.

PMID: 23381111

Abstract:

A tetrabutylammonium iodide catalyzed method for the synthesis of allyl aryl sulfone derivatives with Baylis-Hillman acetates and sulfonylhydrazides using tert-butyl hydroperoxide as an oxidation agent in water has been developed. In this process, the group eliminated from the sulfonyl precursor is molecular nitrogen.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP311284 Tetrabutylammonium iodide Tetrabutylammonium iodide 311-28-4 Price
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