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Tetrabutylammonium Iodide Catalyzed Allylic Sulfonylation of α-methyl Styrene Derivatives With Sulfonylhydrazides

Xiaoqing Li, Xiangsheng Xu, Can Zhou

Chem Commun (Camb). 2012 Dec 28;48(100):12240-2.

PMID: 23147597

Abstract:

Sulfonyl radicals generated from sulfonylhydrazides by the Bu(4)NI-tert-butyl hydroperoxide (TBHP) catalysis system underwent addition to a variety of α-methyl styrene derivatives to give the corresponding allylic sulfones. This selective allylic sulfonylation is metal-free, operationally simple, and environmentally friendly.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP311284 Tetrabutylammonium iodide Tetrabutylammonium iodide 311-28-4 Price
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