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The Chemistry and Properties of Energetic Materials Bearing [1,2,4]Triazolo[4,3-b][1,2,4,5]tetrazine Fused Rings

The Chemistry and Properties of Energetic Materials Bearing [1,2,4]Triazolo[4,3-b][1,2,4,5]tetrazine Fused Rings

Guilong Wang, Tian Lu, Guijuan Fan, Chengqiu Li, Hongquan Yin, Fu-Xue Chen

Chem Asian J. 2018 Dec 4;13(23):3718-3722.

PMID: 30277022

Abstract:

Treatment of heterocyclic amines featuring fused rings of [1,2,4]triazolo[4,3-b][1,2,4,5]tetrazine with fuming HNO3 /P2 O5 leads to six fully characterized explosives through multiple nitration and reduction or oxidation mechanism. Thus, 4-nitro-N-(3-nitro[1,2,4]triazolo[4,3-b][1,2,4,5]tetrazin-6-yl)-1,2,5-oxadiazol-3-amine (3 b, TTDNF) showed high performance (D=9180 m s-1 , P=36.7 GPa) and low impact sensitivity (IS>40 J) while N-([1,2,4]triazolo[4,3-b][1,2,4,5]tetrazin-6-yl)-3-nitro-1,2,4-oxadiazol-5-amine (4 a, TTNOA) exhibited a potential cast explosive component with low melting point at 88.2 °C and high onset decomposition temperature at 226.2 °C.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP90589983	1,1′,4′,1′′-Terphenyl-4-thiol		90589-98-3	Price

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