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The Effect of Constituent Ratios and Varisized Ammonium Salts on the Performance of Two-Dimensional Perovskite Materials

The Effect of Constituent Ratios and Varisized Ammonium Salts on the Performance of Two-Dimensional Perovskite Materials

Haiying Zheng, Huifen Xu, Fangcai Zheng, Guozhen Liu, Xiaoxiao Xu, Shendong Xu, Liying Zhang, Xu Pan

ChemSusChem. 2020 Jan 9;13(1):252-259.

PMID: 31475779

Abstract:

Two-dimensional perovskite solar cells (PSCs) with high moisture resistance are a key topic in the photovoltaic field. However, their lower power conversion efficiencies (PCEs) in comparison to 3 D PSCs is still an urgent problem to be solved. It is vital to understand the impact of constituent ratios and ammonium salt sizes on the photovoltaic performance and humidity stability. Based on the formula of (RNH3 )2 (MA)n-1 Pbn I3n+1 (n=1, 3, 5, 7, 9, and 11), a series of 2 D perovskites is prepared by introducing varisized ammonium salts of ethylammonium iodide (EAI), propylammonium iodide (PAI), and butylammonium iodide (BAI). The effects of the constituent ratios and varisized ammonium salts on the properties of the 2 D perovskites were studied. 2 D perovskite devices based on larger n and smaller ammonium salt size are found to exhibit better performances. However, the moisture resistance of the 2 D perovskite devices is higher when n is smaller and the ammonium salt size is larger. Therefore, the EA2 MA10 Pb11 I34 (n=11) 2 D perovskite device displays the best photovoltaic performance, with the highest PCE of 16.93 %, whereas BA2 MA2 Pb3 I10 (n=3) 2 D perovskite, with the largest contact angle of 79.8°, can retain over 85 % of the initial PCE after 1440 h aging at 50 % relative humidity. This work indicates the PCE and stability of 2 D perovskites can be conveniently and effectively adjusted by controlling the 2 D constituent ratios and ammonium salt sizes, so as to obtain efficient 2 D PSCs with high stability.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP506581	Ethylammonium Iodide		506-58-1	Price

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