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The First Trialkylphosphane Telluride Complexes of Ag(I): Molecular, Ionic and Supramolecular Structural Alternatives

Constantin Daniliuc, Christian Druckenbrodt, Cristian G Hrib, Frank Ruthe, Armand Blaschette, Peter G Jones, Wolf-W du Mont

Chem Commun (Camb). 2007 May 28;(20):2060-2.

PMID: 17713078

Abstract:

The structures of the first phosphane telluride complexes of silver(I), obtained from i-Pr3PTe (1) with AgNMs2 [Ms = SO2CH3] and with AgSbF6, reveal the superior coordinating ability of 1, particularly as a bridging ligand, compared with related i-Pr3PS and i-Pr3PSe ligands.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP12002992 Silver(I) telluride Silver(I) telluride 12002-99-2 Price
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