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The First Tritopic Bridging Ligand 1,3,5-tris(4-carboxyphenyl)-benzene (H3BTB) Functionalized Porous Polyoxometalate-Based Metal-Organic Framework (POMOF): From Design, Synthesis to Electrocatalytic Properties

The First Tritopic Bridging Ligand 1,3,5-tris(4-carboxyphenyl)-benzene (H3BTB) Functionalized Porous Polyoxometalate-Based Metal-Organic Framework (POMOF): From Design, Synthesis to Electrocatalytic Properties

Bao-Xia Dong, Lu Chen, Shi-Yang Zhang, Jun Ge, Liang Song, Hui Tian, Yun-Lei Teng, Wen-Long Liu

Dalton Trans. 2015 Jan 21;44(3):1435-40.

PMID: 25428699

Abstract:

Replacing the metal ions (or metal clusters) in routine MOFs with size-matched polyoxoanions to construct POM-based MOF materials (POMOF) combining well-defined crystalline structures, high surface area, regular and tunable cavities is the great challenge in the current POM chemistry area. In this work, we report a 2-fold interpenetrated porous POMOF, [TBA]6[H3PMo12O40]2[Zn8(BTB)2]·(∼35H2O), which exhibits effective catalytic activity towards bromate reduction, using the methodology of extension for the reduced transition-metal-grafted ε-Keggin polyoxoanions with an expanded tripodal bridging ligand of H3BTB. The simultaneous TGA/DSC-MS technique was applied in this work to identify the evolved gases and was proved to be an effective method for analysing the decomposition process.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP50446441	1,3,5-Tris(4-carboxyphenyl)benzene		50446-44-1	Price

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