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The Henry Reaction in [Bmim][PF₆]-based Microemulsions Promoted by Acylase

Wen-Jian Xia, Zong-Bo Xie, Guo-Fang Jiang, Zhang-Gao Le

Molecules. 2013 Nov 11;18(11):13910-9.

PMID: 24284489

Abstract:

An environmentally-friendly, enzyme-promoted procedure for the Henry reaction was first studied using water-in-[Bmim][PF6] microemulsions as reaction medium. The Amano acylase from Aspergillus oryzae showed better catalytic activity for the addition reactions of nitromethane with a series of aromatic aldehydes, and a highest yield of 90% was obtained.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP9012377-A Amano Acylase Amano Acylase 9012-37-7 Price
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