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Titanium Migration Driven by Li Vacancies in Li(1-x)Ti2O4 Spinel

A Kitada, A M Arevalo-Lopez, J P Attfield

Chem Commun (Camb). 2015 Jul 21;51(57):11359-61.

PMID: 26036215

Abstract:

Gentle oxidation of lithium titanate spinel (LiTi2O4) with water at room temperature gives Li-deficient Li0.33Ti2O4. Combined X-ray and neutron Rietveld analysis shows that 28% of the Ti cations are displaced to alternative octahedral sites, in keeping with a proposed model based on Ti-migration limited by Li-vacancy concentration.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP12031957 Lithium titanate, spinel Lithium titanate, spinel 12031-95-7 Price
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