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Total Synthesis of Carbazomycins A and B

Siyuan Wu, Shinji Harada, Takahiro Morikawa, Atsushi Nishida

Chem Pharm Bull (Tokyo). 2018;66(2):178-183.

PMID: 29386469

Abstract:

Total syntheses of carbazomycins A and B were demonstrated using a ytterbium-catalyzed Diels-Alder reaction with (silyloxyvinyl)indole as a diene. The densely substituted benzene ring of the target compound was successfully constructed by functionalization of a hydrocarbazolone intermediate and subsequent aromatization using N-bromosuccinimide.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP7440644 Ytterbium Ytterbium 7440-64-4 Price
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