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trans-Chloridobis[(Z)-1-imino-1-methoxyethane-κN](triphenylphosphane-κP)platinum(II) Chloride Monohydrate

Daniela Giardina-Papa, Francesco Paolo Intini, Giovanni Natile, Concetta Pacifico

Acta Crystallogr C. 2012 Nov;68(Pt 11):m300-2.

PMID: 23124447

Abstract:

The title compound, [PtCl(C(3)H(7)NO)(2)(C(18)H(15)P)]Cl·H(2)O or trans-[PtCl{Z-HN=C(Me)OMe}(2)(PPh(3))]Cl·H(2)O, crystallizes from an acetone solution of isomeric trans-[PtCl{E-HN=C(Me)OMe}(2)(PPh(3))]Cl. The two HN=C(Me)OMe ligands show typical π-bond delocalization over the N-C-O group [Cini, Caputo, Intini & Natile (1995). Inorg. Chem. 34, 1130-1137] and have the unprecedented Z-anti configuration. The relative orientation of the imino ether ligands is head-to-tail.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP10025657 Platinum(II) chloride Platinum(II) chloride 10025-65-7 Price
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