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trans-Dichloridobis(2,2-dimethyl-prop-ane-1,3-diamine-κN,N')chromium(III) Perchlorate

trans-Dichloridobis(2,2-dimethyl-prop-ane-1,3-diamine-κN,N')chromium(III) Perchlorate

Jong-Ha Choi, Sang Hak Lee, Uk Lee

Acta Crystallogr Sect E Struct Rep Online. 2008 Oct 18;64(Pt 11):m1429.

PMID: 21580872

Abstract:

In the title salt, [CrCl(2)(C(5)H(14)N(2))(2)]ClO(4), the Cr atom is in a trans-CrCl(2)N(4) octa-hedral environment comprising the four N atoms of two chelating 2,2-dimethyl-propane-1,3-diamine ligands and two Cl atoms. The two six-membered CrC(3)N(2) rings in the cation adopt anti chair-chair conformations with respect to each other. The perchlorate anion is disordered over two positions in respect of the Cl and an O atom in a 6:4 ratio. N-H⋯O hydrogen bonds link the cations and anions into a layer structure.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP81190252	7-Diethylamino-2-(7-diethylamino-2-oxochroman-3-yl)chromylium perchlorate		81190-25-2	Price

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