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Tricarbonyl(chlorodiphenylstannyl){η-[2-(dimethylamino)ethyl]cyclopenta-dienyl}molybdenum

Paul J Fischer, Kristina M Krohn, Victor G Young Jr

Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 25;65(Pt 5):m558-9.

PMID: 21583791

Abstract:

Reaction of the tricarbon-yl{η(5)-[2-(dimethyl-amino)eth-yl]cyclo-penta-dien-yl}molybdenum anion and dichlorido-diphenyl-stannane affords the title compound, [MoSn(C(6)H(5))(2)Cl(C(9)H(14)N)(CO)(3)], which exhibits a four-legged piano-stool geometry with chlorido-diphenyl-stannyl ligands unperturbed by the pendant 2-(dimethyl-amino)ethyl groups. The Mo-Sn bond length [2.7584 (5) Å] and the distortion of the tetra-hedral tin coordination geometry are similar to those observed in related tin-substituted tricarbonyl-molybdenum and -tungsten complexes.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP33086667 Hydroxyisopropylcyclopentadienylmanganese(I) tricarbonyl Hydroxyisopropylcyclopentadienylmanganese(I) tricarbonyl 33086-66-7 Price
AP64724294 cis-Tributyl[2-ethoxyethenyl]stannane cis-Tributyl[2-ethoxyethenyl]stannane 64724-29-4 Price
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