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Tris(thio-cyanato-κN)tris-(triphenyl-phosphine oxide-κO)terbium(III)

Tris(thio-cyanato-κN)tris-(triphenyl-phosphine oxide-κO)terbium(III)

Lam N Pham, Anthony T Thames, Frankie D White, Kang Rui Xiang, Richard E Sykora

Acta Crystallogr Sect E Struct Rep Online. 2012 Dec 1;68(Pt 12):m1531.

PMID: 23468740

Abstract:

The title compound, [Tb(NCS)3(C18H15OP)3], contains a six-coordinate Tb(II) cation surrounded by three O-bound triphenyl-phosphine oxide ligands and three N-bound thio-cyanate ligands, each in a fac arrangement. There are two crystallographically unique Tb(III) atoms in the asymmetric unit. One Tb(III) atom resides on a threefold rotation axis, while the other has no imposed crystallographic symmetry. The thio-cyanate ligands are bound through N atoms, illustrating the hard-hard bonding principles of metal complex chemistry.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP12036418	Terbium(III) oxide		12036-41-8	Price

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