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Tuning Mechanism in a Two-Component Columnar Host System Composed of 1,2-diphenylethylenediamine and 1,1'-binaphthyl-2,2'-dicarboxylic Acid

Yoshitane Imai, Kakuhiro Kawaguchi, Katuzo Murata, Tomohiro Sato, Reiko Kuroda, Yoshio Matsubara

Org Lett. 2008 Feb 7;10(3):469-71.

PMID: 18183998

Abstract:

In a two-component columnar host system composed of racemic (rac)-1,2-diphenylethylenediamine and rac-1,1'-binaphthyl-2,2'-dicarboxylic acid, a cavity tuning mechanism resulted from changes in the structure of the columns using a specific combination of the following four molecules: (1R,2R)-1, (1S,2S)-1, (R)-2, and (S)-2.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP29841698 (1S,2S)-(−)-1,2-Diphenylethylenediamine (1S,2S)-(−)-1,2-Diphenylethylenediamine 29841-69-8 Price
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