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Ultrafast Switching Time and Third Order Nonlinear Coefficients of Microwave Treated Single Walled Carbon Nanotube Suspensions

N Kamaraju, Sunil Kumar, B Karthikeyan, Bhalchandra Kakade, Vijayamohanan K Pillai, A K Sood

J Nanosci Nanotechnol. 2009 Sep;9(9):5550-4.

PMID: 19928262

Abstract:

Microwave treated water soluble and amide functionalized single walled carbon nanotubes have been investigated using femtosecond degenerate pump-probe and nonlinear transmission experiments. The time resolved differential transmission using 75 femtosecond pulse with the central wavelength of 790 nm shows a bi-exponential ultrafast photo-bleaching with time constants of 160 fs (130 fs) and 920 fs (300 fs) for water soluble (amide functionalized) nanotubes. Open and closed aperture z-scans show saturation absorption and positive (negative) nonlinear refraction for water soluble (amide functionalized) nanotubes. Two photon absorption coefficient, beta0 approximately 250 cm/GW (650 cm/GW) and nonlinear index, gamma approximately 15 cm2/pW (-30 cm2/pW) are obtained from the theoretical fit in the saturation limit to the data for two types of nanotubes.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
LS71709 Carbon nanotube, single-walled, amide functionalized Carbon nanotube, single-walled, amide functionalized Price
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