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UV-filters and Musk Fragrances in Seafood Commercialized in Europe Union: Occurrence, Risk and Exposure Assessment

UV-filters and Musk Fragrances in Seafood Commercialized in Europe Union: Occurrence, Risk and Exposure Assessment

S C Cunha, L Trabalón, S Jacobs, M Castro, M Fernandez-Tejedor, K Granby, W Verbeke, C Kwadijk, F Ferrari, J Robbens, I Sioen, E Pocurull, A Marques, J O Fernandes, J L Domingo

Environ Res. 2018 Feb;161:399-408.

PMID: 29197758

Abstract:

In the framework of the FP7 ECsafeSeafood project, 62 seafood samples commercialized in Europe Union from several representative species - mackerel, tuna, salmon, seabream, cod, monkfish, crab, shrimp, octopus, perch and plaice - were analysed for residues of 21 personal care products (PCPs), including 11 UV-filters (UV-Fs) and 10 musk fragrances (musks). PCPs analysis were performed by Quick, Easy, Cheap, Effective Rugged, Safe (QuEChERS), combined with liquid-liquid extraction (LLE) or dispersive solid-phase extraction (dSPE), followed by gas chromatography-tandem mass spectrometry (GC-MS/MS). The results showed the presence in a wide range of samples of nine out of eleven UV-Fs compounds analysed, namely 2-ethylhexyl salicylate (EHS), 2-ethylhexyl,4-methoxycinnamate (EHMC), 4-methylbenzylidenecamphor (4-MBC), benzophenone-1 (BP1), benzophenone-3 (BP3), isoamyl-4-methoxycinnamate (IMC), 2,2'-dihydroxy-4,4'-dimethoxybenzophenone (DHMB), homosalate (HS), and octocrylene (OC), whereas galaxolide (HHCB), galaxolide lactone (HHCB-lactone), and tonalide (AHTN) were the most found musks. The potential risks to human health associated with the exposure to eight of the more prevalent PCPs - EHS, EHMC, 4-MBC, BP1, BP3, IMC, HHCB, and AHTN - through seafood consumption were assessed for consumers from five European countries (Belgium, Ireland, Italy, Portugal and Spain). Results showed that the human exposure to UV-Fs and musks estimated from the concentration values found in seafood and the daily consumption of concerned seafood species, were far below toxicological reference values.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP71617102-A	Isoamyl 4-methoxycinnamate		71617-10-2	Price

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