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Versatile Oxidative Approach to Carbazoles and Related Compounds Using MoCl5

Simon Trosien, Philipp Böttger, Siegfried R Waldvogel

Org Lett. 2014 Jan 17;16(2):402-5.

PMID: 24354638

Abstract:

The unique oxidizing power of molybdenum pentachloride provides an easy to perform, versatile, and high yielding method to construct carbazoles and the corresponding dibenzo analogues of thiophene, furan, and selenophene. The coupling reaction tolerates a variety of functional groups. The synthesis is highly modular. By this approach a precursor for the naturally occurring carbazole koenigicine was prepared.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
AP24123920 Koenigicine Koenigicine 24123-92-0 Price
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