Ethyl acetoacetate

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For Research Use Only | Not For Clinical Use
MDL NumberMFCD00009199
Molecular Weight130.14
EC Number205-516-1
REAXYS Number385838
Descriptionanalytical standard
Density1.029 g/mL at 20 °C (lit.)
Solubilitywater: soluble 130 g/L at 20 °C
Assay≥99.0% (GC)
Autoignition Temp.580 °F
BP181 °C (lit.)
Expl Lim9.5 %; gas chromatography (GC): suitable
Gradeanalytical standard
Impurities≤1.0% water
Linear FormulaCH3COCH2COOC2H5
MP−43 °C (lit.)
REAXYS Number385838
Refractive Indexn/D 1.418-1.420
Vapor Density4.48 (vs air)
Vapor Pressure1 mmHg ( 28.5 °C)

1A Novel Method for Quantitative Analysis of Acetylacetone and Ethyl Acetoacetate by fluorine-19 Nuclear Magnetic Spectroscopy

Lulin Zhou, Cheng Li, Xinchu Weng

Magn Reson Chem. 2016 Mar;54(3):222-6.

PMID: 26521683

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1Acetoacetate and Ethyl Acetoacetate as Novel Inhibitors of Bacterial Biofilm

S M Horne, M Schroeder, J Murphy, B M Prüβ

Lett Appl Microbiol. 2018 Apr;66(4):329-339.

PMID: 29341217

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1Metal-free Arylation of Ethyl Acetoacetate With Hypervalent Diaryliodonium Salts: An Immediate Access to Diverse 3-aryl-4(1H)-quinolones

Andrii Monastyrskyi, Niranjan K Namelikonda, Roman Manetsch

J Org Chem. 2015 Mar 6;80(5):2513-2520.

PMID: 25558982

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1Quinolines From the Cyclocondensation of Isatoic Anhydride With Ethyl Acetoacetate: Preparation of Ethyl 4-hydroxy-2-methylquinoline-3-carboxylate and Derivatives

Nicholas G Jentsch, Jared D Hume, Emily B Crull, Samer M Beauti, Amy H Pham, Julie A Pigza, Jacques J Kessl, Matthew G Donahue

Beilstein J Org Chem. 2018 Sep 28;14:2529-2536.

PMID: 30344776

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1RIFM Fragrance Ingredient Safety Assessment, Ethyl Acetoacetate, CAS Registry Number 141-97-9

A M Api, D Belsito, D Botelho, M Bruze, G A Burton Jr, J Buschmann, M L Dagli, M Date, W Dekant, C Deodhar, M Francis, A D Fryer, L Jones, K Joshi, S La Cava, A Lapczynski, D C Liebler, D O'Brien, A Patel, etc.

Food Chem Toxicol. 2019 May 15;127 Suppl 1:S165-S171.

PMID: 30890485

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