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Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2)N,N')zinc

Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2)N,N')zinc

Ali Dehghani, Mostafa M Amini, Ezzatollah Najafi, Azadeh Tadjarodi, Behrouz Notash

Acta Crystallogr Sect E Struct Rep Online. 2012 Jun 1;68(Pt 6):m811.

PMID: 22719356

Abstract:

The reaction of equimolar amounts of zinc bromide and 2,9-dimethyl-1,10-phenanthroline in dry methanol provided the title compound, [ZnBr(2)(C(14)H(12)N(2))], in good yield. The Zn(II) ion is coordinated in a distorted tetra-hedral environment by two N atoms from the chelating 2,9-dimethyl-1,10-phenanthroline ligand and two bromide ions. There is inter-molecular π-π stacking between adjacent phenanthroline units, with centroid-centroid distances of 3.594 (3) and 3.652 (3) Å.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP7699458	Zinc bromide		7699-45-8	Price

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