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Palladium and Platinum 2,4- cis-amino Azetidine and Related Complexes

Palladium and Platinum 2,4- cis-amino Azetidine and Related Complexes

Akina Yoshizawa, Antonio Feula, Andrew G Leach, Louise Male, John S Fossey

Front Chem. 2018 Jun 21;6:211.

PMID: 29977888

Abstract:

Seven N,N'-palladium(II) chloride complexes, one N,N'-palladium(II) acetate complex of 2,4-cis-azetidines where prepared and analyzed by single crystal XRD. Two platinum(II) chloride N,N'-complexes of 2,4-cis-azetidines where prepared and analyzed by single crystal XRD. Computational analysis and determination of the %Vbur was examined conducted. A CNN' metallocyclic complex was prepared by oxidative addition of palladium(0) to an ortho bromo 2,4-cis-disubstituted azetidine and its crystal structure displays a slightly pyramidalized metal-ligand orientation.

Chemicals Related in the Paper:

Catalog Number	Product Name	Structure	CAS Number	Price
AP7647101	Palladium(II) chloride		7647-10-1	Price

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